In the Paint panel or Brush Options window set Brush Mode.
See also Sketch on a Cintiq.
In the Paint Panel or Brush Options window do any of the following:
You can also set Brush Mode to smear paint (Smear), blur paint (Blur), sharpen paint (Sharpen), lighten paint (Dodge) or darken paint (Burn). See Blur paint, Sharpen paint, and Smear paint.