Choose Paint Edit > Layer Effect > Sharpen Layer or choose a brush from Paint > Effectbrush > Sharpen Brush and use the brush to sharpen paint.
To sharpen all unmasked paint on an image layer
To set the amount of sharpening, choose Paint Edit > Layer Effect > Sharpen Layer ❒ to open the Sharpen Layer Options box and adjust the Sharpness from 0 (no sharpening) to 10 (maximum sharpening). To set the extent that each pixel is sharpened, set the Strength from 0 to 4.
To set the amount of sharpening, open the Brush Options window (for example, choose Paint > Effectbrush > Sharpen Brush ❒) and adjust the Sharpness from 0 (no sharpening) to 10 (maximum sharpening). To set the extent that each pixel is sharpened, set the Sharpen Strength from 0 to 4.