You can activate the mental ray renderer for the entire scene, or for specific passes.
To activate the mental ray renderer for the entire scene
The Render Manager > Scene Render Options
From the Render toolbar, choose Render > Render > Scene Options
On the Scene Globals tab, set the Scene Renderer to mental ray.
To activate the mental ray renderer for a pass
The Render Manager > (select a pass)
Set the current pass and choose Render > Render > Pass Options or Pass > Edit > Edit Current Pass from the Render toolbar.